ECOpole’25 – Conference Program
ECOpole Conference

ECOpole’25 Programme

34th Central European Conference
October 22–24, 2025 | Technical University of Liberec, Czech Republic
Bendlova 1409/7, Venue – building L (CXI)
Water–Food–Energy Nexus: Pathways to Sustainability
Wednesday, October 22, 2025 — Arrival Day
17:00 — 21:00
Participant arrival and registration
Informal networking and poster setup | Welcome reception with Czech culinary specialities
Thursday, October 23, 2025 — Water & Energy Themes (4th floor, CXI)
08:30 — 09:00
Breakfast
09:00 — 09:05
Opening of the Conference
dr hab. inż. Stanisław Wacławek (Chairman of the Organising Committee)
Biosilica; A New Generation Nanomaterial Obtained from the Aquatic Environment
Bogusław Buszewski¹,², H. Al-Saoud¹,², M. Szumski³, M. Sprynskyy²
¹Prof. Jan Czochralski Kuyavien-Pomeranian Research and Development Center, ul. Krasińskiego 4, 87 100 Toruń, PL
²Department of Environmental Chemistry and Bioanalytics, Faculty of Chemistry Nicolaus Copernicus University (NCU) in Torun, PL
³Interdyscyplinary Center of New Technology, NCU in Torun, ul. Gagarina 7, Pl-87 100 Toruń, PL
Silica is a widespread mineral that enjoys constant interest from material engineering specialists, environmental scientists and chemists. This substance is described by the stoichiometric formula as SiO₂, and also in the hydrated form as SiO₂·nH₂O. An alternative to the currently commonly used synthetic silica is biosilica obtained as a result of biogenic processes, in an aqueous environment, with the participation of selected strains of microorganisms — algae. This material, unlike synthetic products, is characterized by a micro- diatoms of silica sponges with orthosilicate units, in which two silanol groups are connected in one bond or siloxane. Its purity in terms of chemical composition, chemical and mechanical stability and resistance is guaranteed by excellent repeatability of biosynthetic processes, which are also characterized by high specificity and low unit cost. The paper presents the aquatic conditions of silica biosynthesis used as an adsorbent and carrier of stationary phases (chemically bonded phases with different functional groups) in liquid chromatography and related techniques. Characterization of bare and modified material using porosimetric techniques (low-temperature adsorption, nitrogen desorption), microscopic imaging (SEM, TEM, AFM), characterization of surface architecture using spectral and spectroscopic methods (FTIR, CP MAS NMR, XRD, ICP-MS, Ramman) and chromatography will be discussed. Potential application possibilities (first reports in the literature) in chromatographic separation in different modes and sample preparation will also be presented. Acknowledgement: The work was co-financed by the project “Advanced biocomposites for tomorrow’s economy BIOG-NET”, FNP POIR.04.04.00-00-1792/18-00, the project is carried out under the TEAM-NET program of the Foundation for Polish Science co-financed by the European Union under the European Regional Development Fund.
Keywords: aquatic ecosystem, algae, biosilica, material chemistry, analytical chemistry, separation sciences, instrumentation, miniaturization, sample preparation, green chemistry
Trends and Advances in (Advanced) Oxidation Processes
Prof. Holger Lutze
Department of Civil and Environmental Engineering, Institute IWAR, Chair of Environmental Analytics and Pollutants, Technical University of Darmstadt, Franziska-Braun-Straße 7, Darmstadt 64287, Germany
Oxidation processes are an important tool in wastewater treatment. The combination of chlorination and sand filtration was first time applied at around 1900 and resulted in a great improvement of the water quality by elimination of pathogens and taste and odor. In 1970s adverse disinfection by-products and few years later transformation products have been discovered. This initiated large research activities creating a sound mechanistic understanding on structure related reaction kinetics and transformation product formation for several oxidants. Based on this data prediction models using quantitative structure activity relationships (QSAR) and quantum mechanics are becoming increasingly successful. These approaches accelerate advances in research and application to develop safe and energy efficient treatment oxidation processes. Yet prediction models cannot deal well with the water matrix which controls the oxidant exposure, the formation of secondary oxidants and formation of transformation- und by-products and their biological effect and behavior in follow-up treatment steps and the environment. The talk will present the effect of the water matrix on formation pollutant degradation and disinfection in oxidation processes.
Keywords: Oxidation Processes, secondary oxidants, mechanisms, disinfection
Design and Applications of MOF-derived Hierarchical Materials for Aqueous Environmental Catalysis and Biomass Valorization
Kun-Yi Andrew Lin
¹Department of Environmental Engineering, National Chung Hsing University, Taiwan
²Innovation and Development Center of Sustainable Agriculture (IDCSA), National Chung Hsing University, Taiwan
This presentation explores the design and applications of 3D and hierarchical Metal-Organic Framework (MOF) composites as catalysts for pollution control and biomass valorization (upgrading). Emphasis is placed on the development of various MOF-based materials, including the HKUST-1 mesh, which demonstrates exceptional catalytic performance in transforming biomass-derived substrates into valuable chemicals. Key structural and functional attributes of these materials, such as enhanced surface areas, tunable porosity, and hierarchical architectures, will be discussed in the context of their applications in aqueous environmental catalysis. Through case studies and analyses, the innovative potential of MOF composites in advancing sustainable chemical processes and green technologies will be highlighted, providing valuable insights into their role in addressing environmental and resource challenges.
Keywords: MOFs, 3D composites, HKUST-1, ZIF, aqueous environmental catalysis, biomass conversion
10:50 — 11:20
Coffee Break

From Global Contamination to Advanced Treatment: Benzophenone-1 Degradation by Thermally Activated Peroxydisulfate
Lenka McGachy¹*, Radek Škarohlíd¹, Pavlína Těšínská¹, Adam Loos¹, Abir Melliti¹, Klára Anna Mocová¹, Tomáš Kulda¹, Martina Navrátilová¹, Mario Vazdar², Katarina Vazdar³, Jiří Kosina⁴, Jan Tarábek⁵
¹Department of Environmental Chemistry, University of Chemistry and Technology Prague, Technická 5, 16628, Prague, Czech Republic
²Department of Mathematics, University of Chemistry and Technology, Technická 5, 16628, Prague, Czech Republic
³J. Heyrovský Institute of Physical Chemistry, Czech Academy of Sciences, Dolejškova 2155/3, 182 00 Prague 8, Czech Republic
⁴Mass Spectrometry Laboratory, University of Chemistry and Technology, Technická 5, 16628, Prague, Czech Republic
⁵Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo náměstí 542/2, 16610 Prague, Czech Republic
The ubiquitous presence of organic UV filters from personal care products poses an escalating environmental challenge. Benzophenones—whose parent compounds degrade to benzophenone-1 (BP1)—are widely detected worldwide, even in remote regions, and exhibit pseudo-persistence and endocrine-disrupting effects. Transformation products such as BP1 may be more toxic than their precursors, while conventional wastewater treatment is largely ineffective at removing them. This work evaluates thermally activated peroxydisulfate (S2O82−) as a quaternary treatment for BP1 in water. Operational parameters were optimized and degradation pathways were elucidated by combining experiments with density functional theory calculations, clarifying the roles of reactive radical species. Matrix effects of dissolved solutes on treatment efficiency were assessed, and the toxicity of treated solutions was evaluated. The results provide mechanistic insight and practical guidance for implementing robust, sustainable strategies to mitigate UV-filter micropollutants in aquatic environments.
Keywords: Organic UV filters; Benzophenone-1 (BP1); Advanced oxidation processes (AOPs); Heat-activated peroxydisulfate; Degradation pathways

Turning Waste into Clean Water: Post-Coagulation Sludge as Dye Adsorbent
M. Pająk, A. Dzieniszewska
Institute of Environmental Engineering Polish Academy of Sciences, Zabrze, PL
The removal of dye pollutants from water and wastewater remains a critical environmental issue, particularly in light of sustainable water resource management and circular economy principles. The textile industry, a major contributor to water contamination, discharges dyes that are often persistent, toxic, and resistant to biodegradation. Although various treatment methods—such as adsorption, coagulation, ion exchange, and advanced oxidation—are commonly employed, their effectiveness and cost-efficiency vary considerably. In particular, many rely on expensive or non-renewable materials, prompting growing interest in alternative, waste-based adsorbents. Post-coagulation sludge, a byproduct of drinking water treatment processes, has gained attention as a promising sorbent material. These sludges, typically treated as waste, are rich in metal oxides and possess favorable surface properties that support dye adsorption. Their reuse not only helps address the issue of sludge disposal but also aligns with circular economy strategies by transforming waste into a valuable resource for environmental protection. In this study, the adsorption potential of post-coagulation sediments from a water treatment plant was assessed for the removal of Acid Blue 193, an anionic dye commonly used in textile processing. Adsorption experiments were performed using the batch method, evaluating the influence of various process parameters such as adsorbent dosage, initial dye concentration, contact time, and solution pH. The maximum adsorption capacity achieved confirmed the sediments’ high efficiency in removing the dye. Experimental data were analyzed using three adsorption isotherm models—Langmuir, Freundlich, and Dubinin–Radushkevich—while kinetic studies indicated that the process followed a pseudo-second-order model, suggesting a chemisorption mechanism. The findings confirm that post-coagulation sediments can serve as an effective, low-cost adsorbent for removing Acid Blue 193 from aqueous solutions. Their utilization supports both sustainable sludge management and the development of environmentally responsible water treatment technologies.
Keywords: post-coagulation sludge, adsorption, dyes removal, Acid Blue 193
Acknowledgement: This work was supported by the Polish Ministry of Education and Science – statutory research of the Institute of Environmental Engineering Polish Academy of Sciences no. 1a-154/25.

Biopolymer Solutions for Wastewater Treatment – Application of Modified Lignin Adsorbent
A. Dzieniszewska¹, M. Pająk¹, J. Czupioł¹, J. Nowicki², G. Rzepa³
¹Institute of Environmental Engineering Polish Academy of Sciences, Zabrze, PL
²Łukasiewicz Research Network – Institute of Heavy Organic Synthesis “Blachownia”, Kedzierzyn-Kozle, PL
³AGH University of Krakow, Krakow, PL
The rapid growth of civilization worldwide, including population increase, industrialization, and urbanization, has led to rising levels of waste and pollution, negatively affecting both soil and water environments. To address these challenges and improve the quality of water resources, strong emphasis has been placed on the development and advancement of wastewater treatment technologies, including adsorption methods. In recent years, there has been growing interest in exploring bio-based materials as low-cost, eco-friendly adsorbents, as they are renewable, widely available, and exhibit desirable biological and chemical properties that enable them to effectively bind contaminants. Lignin is one of the most abundant natural polymers, generated in large quantities as a by-product of the pulp and paper industry. Its application as a biosorbent offers a sustainable approach to lignin valorization. Due to its specific structure and the presence of functional groups such as hydroxyl and carboxyl, lignin can be chemically modified to enhance its physicochemical and adsorption properties. The aim of this study was to evaluate the effect of lignin modification using imidazolium-based ionic liquids on its adsorption capacity toward heavy metal ions. Adsorption capacity tests, conducted before and after modification, were performed under static solid-liquid contact conditions, taking into account various process parameters such as pH, adsorbent dose, initial metal concentration, and contact time. To interpret the experimental results, isotherm models and kinetic equations were applied. The results demonstrated that lignin modification had a significant effect on its adsorption performance, substantially increasing the removal efficiency of metal ions. These findings suggest that modified lignin can be considered a promising alternative adsorbent for wastewater treatment applications.
Keywords: Modified lignin, Ionic liquids, Adsorption, Heavy metals
Acknowledgement: This work was supported by the Polish Ministry of Education and Science – statutory research of the Institute of Environmental Engineering Polish Academy of Sciences no. 1a-143/23 and Łukasiewicz Research Network – Institute of Heavy Organic Synthesis “Blachownia”.
Rainwater (harvesting) and Circular water management as a tool for urban water resources management: Case studies from Life4zoo and MAURICE project
Tomáš Lederer1, Magda Nechanická1, Tomáš Dufek1, Martin Palušák1, Lenka Čápová2, Petr Kvapil3
1Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, 461 17, Liberec, Czech Republic
2Zoo Liberec, Liberec, Czech Republic
3Photon Water, Czech Republic
Water is one of the basic, priority, and crucial raw materials for meeting the economic, social, and environmental needs of society not in the EU and worldwide. Water determines the conditions for a sustainable environment and national economy worldwide now and for ages. Water is life. The main objective of the lecture is to introduce ongoing research and implementation actions that promotes the concept of European Green Deal in the area of “circular economy” and responsible urban Water management impacted by climate changes. This “circular Water management” means multiple cycles of water use and reprocessing within a single user footprint instead of a single linear use of water from the supply, single application (such as domestic use) to the sewer. Circular water management has the benefits of reducing demand on primary water resources, mitigating costs for users and together with rain and storm water management, reducing loading on sewerage systems, and having multiple synergies with improved energy and resource utilization. Circular water use will be a major contributor to a more effective, adaptable, and resilient water sector able to better cope with coming global climate change impacts. Life4zoo project is demonstration project focused on implementation of Circular Water management in areas of zoo like visitor attraction by application of Natural Based solution with high-tech technologies for post-treatment. MAURICE is Central Europe Interreg project focused on Urban Water resources management with the aim to increase resilience of EU countries to extreme weather events as urban droughts and floods as well as depletion of urban groundwater resources, where rain and stormwater management is the crucial tool.
Keywords: Circular water management, water reuse, rainwater harvesting and treatment, sanitation of treated water

Mathematical Environmental Risk Modeling, Cross-Border Curricular Internships, New Approaches
A. Lyčka1, V. Štěpánek1, L. Hyšplerová1, S. Eminger2, J. Kříž1, A.B. Dołhańczuk-Śródka3
1University of Hradec Králové, Hradec Králové, Czech Republic
2EMPLA AG, Hradec Králové, Czech Republic
3University of Opole, Opole, Poland
At previous conferences, we have reported that regular mathematical modelling of emission dispersion from major sources—also applied in risk assessments to predict toxic releases from various technologies and, in some cases, potential terrorist incidents—is a legal requirement in all EU member states. Despite this, most EU countries face a shortage of specialists in this highly specific and demanding field. Our earlier contributions addressed innovations in the teaching of environmental emission dispersion modelling, its principles and algorithms, as well as the convergence of CZ–PL cross-border environmental education in the technical natural sciences. In this presentation, we report on compelling results from our pedagogical research into environmental-technical higher education, carried out within a four-year PL–CZ EU-funded project entitled “Cooperation between the University of Opole and the University of Hradec Kralove increasing the employability of graduates on the cross-border labour market” and its subsequent three-year sustainability phase. Through qualitative research methods, we confirmed the critical role of internships in motivating students to pursue activities in this domain. These findings are discussed within the framework of contemporary trends in university–industry collaboration as practiced by leading higher education institutions worldwide.
Keywords: mathematical environmental risk modeling, curricular internships, qualitative pedagogical research

Cross-Border Wastewater Solutions: Polish-Czech Interreg Partnership — An Extended Discussion
V. Leová1, A. Dzieniszewska2, J. Nowicki3, R. Kulesza3, J. Kyzioł-Komosińska2, M. Pająk2, J. Czupioł2, M. Zarębska3,4, T. Lederer1, S. Wacławek1
1Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, 461 17, Liberec, Czech Republic
2Institute of Environmental Engineering Polish Academy of Sciences, Zabrze, Poland
3Łukasiewicz Research Network- Institute of Heavy Organic Synthesis “Blachownia”, Kędzierzyn-Koźle, Poland
4Silesian University of Technology, Faculty of Chemistry, Department of Inorganic, Analytical Chemistry and Electrochemistry, Gliwice, Poland
Micropollutants, such as pharmaceuticals, per- and polyfluoroalkyl substances, or heavy metals, can pose significant risks to the environment and human health. They are readily transported by water and accumulate in aquatic ecosystems. To address this challenge, our project unites the expertise of Czech and Polish scientific institutions and partners to improve the monitoring and removal of micropollutants from wastewater. The initiative combines cross-border monitoring, development and testing of advanced removal technologies, and creation of a shared database to support evidence-based decision-making. Through collaboration and knowledge exchange, the project aims to enhance wastewater treatment and protect water quality in the CZ–PL border region.
Keywords: Micropollutants, Wastewater Treatment, Cross-Border Cooperation, CZ–PL Region, Monitoring, Removal Technologies
13:30 — 14:45
Lunch (and a group photo)
Nano and Microrobots for Environmental Remediation
Martin Pumera
CEITEC — Brno University of Technology, Czech Republic
Microrobots are rapidly gaining attention as powerful instruments for environmental remediation. Operating at the nano- to microscale, these autonomous machines can: a) Eliminate trace organic pollutants such as hormones; b) Catalytically degrade pesticides and nitroaromatic compounds; c) Adsorb and degrade micro- and nanoplastics from aquatic systems; d) Disrupt and remove resilient biofilms. This talk highlights the innovative designs, propulsion strategies and reaction mechanisms that underpin these capabilities, surveys recent proof-of-concept demonstrations, and assesses the key technological and regulatory challenges that must be addressed before large-scale deployment. Finally, it outlines promising research directions and sketches a roadmap for translating microrobotic technologies into sustainable, real-world solutions.
Keywords: Microrobots, environmental remediation, autonomous systems, pollutant degradation, microplastics, biofilms, aquatic systems, propulsion strategies
Turning Waste into Energy: Photocatalytic Hydrogen Generation Coupled with Wastewater Treatment under Solar Light
Laura Clarizia
Department of Chemical, Materials and Industrial Production Engineering, University of Naples “Federico II”, p.le V. Tecchio 80, 80125 Napoli, Italy
Photocatalytic and photoelectrocatalytic water splitting and organic reforming using nanoscale semiconductors hold significant promise for sustainable hydrogen production by harnessing solar energy with minimal environmental impact. The incorporation of industrial and urban wastewater streams containing specific organic compounds (e.g., carboxylic acids and alcohols) enables a dual-purpose process: concurrent wastewater treatment and hydrogen generation. Despite extensive research over recent decades to develop materials capable of efficiently capturing solar energy, the current solar-to-hydrogen conversion efficiency remains insufficient for widespread economic viability in real-world applications. This presentation provides a comprehensive overview of photocatalytic water splitting and organic photoreforming, with a focus on low cost titania-based semiconductor nanomaterials (e.g., Cu/TiO₂-based photocatalysts) employed as photocatalysts for hydrogen production in aqueous media under UV and visible light. To identify economically viable and efficient metal-based semiconductor nanomaterials for photoreforming of organic compounds, several critical parameters for optimizing photocatalytic composites for visible-light-driven water splitting and organic reforming are evaluated. These include band gap energy and potentials, photostability in aqueous environments, crystallinity, particle size, and specific photoactivity. The role of sacrificial organic compounds in the photoreforming process is also examined, and potential reaction mechanisms are proposed. Finally, a critical review of recent findings on the kinetics of photocatalytic hydrogen evolution over metal-based semiconductor nanophotocatalysts is presented. This investigation aims to lay a solid foundation for the development of innovative, efficient, and cost-effective metal-based semiconductor nanomaterials for hydrogen generation via solar-driven organic reforming of wastewater streams from urban and industrial sources.
Keywords: photocatalysis; solar energy; hydrogen production; wastewater treatment
16:15 — 16:45
Coffee Break
Smart Integration of Energy and Water Systems for Sustainable Urban Infrastructure
Prof. Kourosh Behzadian
University of West London, UK
Urban infrastructure is being reshaped by concurrent pressures such as rapid urbanisation, uneven access to safe water, climate-driven variability, the energy crisis, and ageing assets, while energy and water utilities pursue accelerated decarbonisation (e.g., the UK utility sector’s ambition to reach net zero well before 2050). These forces make siloed planning untenable and call for sector coupling: co-optimising energy and water as an intelligent, integrated cyber-physical system can deliver greater resilience, equity, and emissions reductions at lowest cost. This presentation reviews the framework and the requirements needed to achieve it.
Keywords: energy systems, water systems, urban infrastructure, smart integration
Towards Biodegradable Photonic Technologies for Minimalistic, Sustainable Information Storage
S. Schellhammer, H. Thomas, T. Achenbach, S. Reineke
Technische Universität Dresden, Faculty of Physics, Dresden, Germany
In the field of Organic Electronics, biodegradability of semiconducting devices, such as solar cells, light-emitting diodes, and transistors, is often emphasized as a potential of this technology. However, functional biodegradable prototypes are widely missing. Even more minimalistic yet powerful are photonic solutions from purely organic materials. Here, for example, oxygen-sensitive phosphorescent emission can be used as a switch, enabling the development of programmable luminescent tags (PLTs) for applications in the fields of sensor technology, labelling, and information exchange. We present the design of PLTs made from biodegradable or at least industrially compostable, commercially available materials (bioPLTs). As natural emitters, quinoline alkaloids show sufficient phosphorescence when embedded in a polymer matrix, combined with weak fluorescence in the UV for excellent contrast during readout. Polylactic acid provides a promising solution for both the matrix material and the flexible substrate. Phosphorescence can be locally controlled by the oxygen concentration in the film by using the polyvinyl alcohol Exceval as additional oxygen blocking layers. These bioPLTs exhibit all function-defining characteristics also found in their regular non-compostable analogs. With this work, we present a promising technology for compostable information storage and sensing devices.
Keywords: sensing, anticounterfeiting, food labels, photophysics, nanotechnology

Photovoltaic-Driven Reverse Osmosis for Rural Desalination: A 25-Year Water–Energy Nexus System Dynamics Model
Mohammad Gheibi
Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, 461 17, Liberec, Czech Republic
Solar-powered reverse osmosis delivers drinking water to remote communities while cutting grid dependence and emissions, aligning energy–water planning for resilience, affordability, and SDG progress. A comprehensive system-dynamics model of a community-scale solar-powered reverse osmosis (PV-RO) desalination plant for Kalile Village, Zahedan (Iran), is developed to evaluate the coupled water–energy–carbon–cost interactions over a 25-year period. The model integrates stochastic solar resource generation (DNI/DHI/GHI using Markov weather transitions), a detailed photovoltaic array with thermal, optical, shading, and inverter losses, and an RO subsystem incorporating recovery efficiency (75%), salt rejection, pressure dynamics, and fouling–cleaning cycles. A techno-economic and carbon assessment layer quantifies life-cycle costs and emissions. The optimized 90 kWp PV array (≈236 modules) generates approximately 146 MWh annually, achieving water production with total dissolved solids near 46 mg L⁻¹, well below the WHO standard (1000 mg L⁻¹). Specific energy consumption remains within 0.7–0.9 kWh m⁻³, ensuring sustainable water supply for around 4,000 residents. Lifecycle evaluation reveals an avoidance of nearly 1.5 kt CO₂ over 25 years relative to fossil grid electricity. Economic analysis confirms positive NPV, double-digit IRR, and mid-term payback, while the levelized cost of water remains competitive for rural applications. Sensitivity results identify panel tilt as the most influential parameter (~1.5% energy change per 1% tilt variation). The findings demonstrate the long-term viability of PV-RO systems for decentralized, low-carbon, and resilient water supply in arid regions.
Keywords: Solar-Powered Desalination; Water-Energy Nexus; System Dynamics Simulation; Sustainability Assessment; Techno-Economic Optimization

Changes in the energy storage market
A. Zaremba¹, T. Rodziewicz², M. Wacławek³,⁴
¹Czestochowa University of Technology, Czestochowa, PL
²University of Opole, Opole, PL
³Ecological Chemistry and Engineering Society, Opole, PL
⁴European Academy of Sciences and Arts, Salzburg, AT
Authors describe changes in the energy storage market with particular emphasis on changes in energy storage prices, their availability and changes in the types of storage facilities installed. The authors present a summary of the data and, where possible, try to present future trends.
Keywords: energy, storage, market, prices, trends
Friday, October 24, 2025 — Food, Cross-Cutting Nexus & E-Session
08:30 — 09:00
Breakfast
09:00 — 13:00
Parallel Sessions
Room A (4th floor, CXI) — Food Theme:
09:00-09:30: Prof. Miroslav Černík – “Application of tree gums in environmental and food applications”
09:45-10:30: Prof. Tzong-Ru Lee – “Implementing Nexus-Based Agri-Food Integration”
10:30-11:00: Coffee Break
11:00-12:00: Oral Session III — Food: Sustainable Agriculture and Packaging Innovations
12:00-13:00: Young Researchers Forum

Room B (2nd floor, CXI) — E-Session:
09:00-09:45: Prof. Mincong Tang – “Navigating China’s Green Transition” (Opening E-Session)
09:45-12:00: Geely E-Session Digital Economy and Environmental Sustainability
12:00-12:30: Prof. Majeti Prasad – “Climate Change Impacts on Water-Energy-Food Nexus” (Online Keynote)
12:30-12:45: Prof. Ágnes Bálint – “The Effect of Wildflower Gardens on Biodiversity” (Online Oral)
Application of tree gums in environmental and food applications
Prof. Miroslav Černík
Technical University of Liberec, Liberec, CZ
Tree-derived carbohydrate gums are versatile, eco-friendly materials used not only as food additives but also for diverse non-food applications. They enable the green preparation of nanoparticles, nanofibers, sponges, films, and composites, and have been applied to stabilize metal, nonmetal, bimetallic, and carbon nanostructures. Renewable gum-based products produced by electrospinning, solution casting, self-assembly, or lyophilization show enhanced physicochemical, mechanical, and barrier properties when combined with inorganic, organic, or nanoparticle additives. These materials are being explored for environmental remediation, water purification, food packaging, energy devices, tissue engineering, regenerative medicine, and corrosion protection, highlighting their role as low-cost, sustainable platforms for future technologies.
Keywords: tree gums, packaging material, self-assembly, eco-friendly materials
Navigating China’s Green Transition: The Coupled Dynamics of Digital Economy, Industrial Transformation, and Carbon Emissions
Mincong Tang
The International Center for Informatics Research of Beijing Jiaotong University, Beijing, CN
Under the dual drivers of China’s “dual carbon” goals and rapid digital economy expansion, understanding the interplay among digitalization, industrial transformation, and carbon emissions is critical. However, the mechanisms linking these three systems remain underexplored. This study constructs a ternary analysis framework (D-I-C system) integrating the digital economy, industrial structure transformation, and carbon emissions, and employs a modified coupling coordination model, spatial econometric analysis, and a panel vector autoregressive (PVAR) model to investigate their spatiotemporal dynamics across 30 Chinese provinces from 2013 to 2022. The results reveal that: (1) the coupling coordination degree exhibits a regional gradient, with high coordination clusters emerging in the Yangtze River Delta and Pearl River Delta regions; (2) significant self-reinforcing effects exist within each subsystem, with industrial structure transformation acting as a key intermediary through factor reallocation and technology substitution; and (3) a long-term dynamic transmission path of “digital economy → industrial upgrading → carbon emission reduction” underpins the progressive decarbonization of the economic system. Based on these findings, this study proposes differentiated regional governance strategies, enhanced industrial transformation hubs, and the activation of digital low-carbon synergies to support China’s sustainable development transition. The insights contribute to understanding the complex systemic interactions crucial for reconciling digitalization and carbon reduction in emerging economies.
Keywords: digital economy; industrial transformation; carbon emissions; coupling coordination; sustainable development; spatial econometrics
Implementing Nexus-Based Agri-Food Integration: From Source to Table and Beyond
Tzong-Ru Lee
National Chung Hsing University, Taiwan
The intricate interconnections among Water–Food–Energy (WFE) systems are increasingly recognized as a cornerstone for advancing global sustainability and climate adaptation. Building a resilient and sustainable agri-food system requires the integration of water resource management, agricultural production, and energy use, governed through frameworks that promote cross-sectoral collaboration and systemic resilience. However, a critical global challenge persists: transforming the Nexus concept from a theoretical paradigm into actionable and context-sensitive operational models. This study presents 5 enterprise-based cases, each corresponding to one of the WFE Nexus pillars—water, food, and energy—to illustrate how locally embedded innovation can drive systemic integration while aligning with the United Nations Sustainable Development Goals (SDGs 2, 6, 12, and 13). These cases demonstrate that when Nexus principles are embedded in corporate operational strategies and system design, they enable scalable, transferable models for sustainability. Such approaches pave viable pathways from place-based action toward global sustainable transitions.
Keywords: Water-Food-Energy nexus, agri-food systems, sustainability integration, SDGs, enterprise-based models, systemic resilience, climate adaptation, operational frameworks
Study on the Degradation of Oxytetracycline in Water by Cobalt-Modified Macadamia Nut Shell Biochar Activated Persulfate
Yi Ding
Southwest Jiaotong University

Micro-flake-like Copper Sulfide as High-performance Anode Material for Sodium-ion Batteries
Fuyou Chen, Lin Xi, Bo Tan
Geely University of China
Transition metal sulfides possess a relatively high theoretical specific capacity and are frequently considered as candidate anode materials for sodium-ion batteries. Nevertheless, the substantial volume effect during the cycling process can cause the electrode materials to pulverize or experience structural collapse. This directly results in a rapid decline in the battery’s capacity and lifespan. Nanotechnology and carbon coating are effective strategies for addressing this issue. In this research, a CuS micro-flower-like structure composed of thin nanosheets was designed and synthesized. The thin nanosheet structure can effectively mitigate the volume expansion during the cycling process. The micro-flower-like CuS, when used as the anode materials for sodium-ion batteries, can still deliver a specific capacity of 312 mAh/g after 8000 cycles at a current density of 5 A/g, demonstrating excellent electrochemical performance.
Keywords: Micro-flake-like; Anode materials; CuS; nanocrystallization; Sodium-ion batteries

Design and Implementation of a Water Quality Safety Data Analysis System Based on Data Mining
Zhang Hao, Tan Bo, Xie Zhenyu, Yu Ting
College of Sports and Health, Geely University, Chengdu, Sichuan 641423
With the deepening of industrialization and urbanization, water pollution has become a major challenge threatening ecological environments and public health. Traditional water quality monitoring methods suffer from limitations such as low efficiency, poor timeliness, and difficulty in predicting macro trends. This paper designs and implements a water quality safety data analysis system based on data mining, aiming to enhance the scientificity and intelligence of water quality monitoring through big data analysis and artificial intelligence technologies. The system performs data cleaning and feature engineering on raw water quality data to ensure data quality; subsequently constructs high-precision prediction models using algorithms including random forest, XGBoost, and LightGBM, while optimizing performance through recursive feature elimination and Bayesian optimization. It also introduces the SMOTE algorithm to address data imbalance issues, significantly enhancing the model’s ability to identify unsafe water samples. Based on the Flask framework, the system develops an integrated web application featuring user management, data visualization, and water quality prediction functions, providing intuitive decision-making tools for managers and the public.
Keywords: data mining; water quality safety; machine learning; visual analysis; prediction system; Flask

Analysis and Prediction of Water Quality Monitoring Data Based on Machine Learning
Lu Junjie, Lai Chuangxin, Chen Siqi
Geely University of China, School of Intelligence Technology, Chengdu, Sichuan 641423
With the growing demand for water environment protection, water quality monitoring and prediction has become essential for safeguarding resources. This study analyzes and predicts water quality data using machine learning. Based on a simulated dataset, models for dissolved oxygen (DO) and pH were built with linear regression, random forest, and XGBoost. The results show XGBoost achieves the highest accuracy and better trend fitting, effectively capturing nonlinear variations. Random forest performs moderately, while linear regression shows large deviations at extreme values. Feature importance analysis indicates that DO is mainly influenced by BOD, temperature, and ammonia nitrogen, while pH is driven by alkalinity, hardness, and ammonia nitrogen, aligning well with known water environment patterns. These findings demonstrate that machine learning improves prediction accuracy and supports scientific water quality management and decision-making.
Keywords: water quality monitoring; machine learning; XGBoost

Research on the Assessment of the Resilience of China’s Water Resource System and Multi-Objective Coordinated Optimisation Pathways
Na Tang, Y. Jian
Geely University of China

Vocational Education Empowering Sustainable Rural Governance: A Human–Technology Integrated Model
Li Jing, Yu Jiajia
School of Finance and Business, Chongqing Jianzhu College, Chongqing, 400072, China
Under the dual background of the rural revitalization strategy and the “dual carbon” goals, the management of rural collective “Three Assets” (funds, assets, and resources) and the development of new agricultural business entities have become key supports for sustainable rural governance. However, challenges remain, including weak institutional implementation, delayed digitalization, and insufficient human capacity, which restrict the growth of collective economies and the digital upgrading of agricultural entities. Vocational education, with its applied orientation and close alignment with industry and grassroots needs, holds unique advantages in addressing these deficits. Based on surveys, interviews, and field observations in counties of Chongqing, this study identifies common dilemmas in “Three Assets” management and the development of agricultural business entities, and proposes a Human–Tech Integrated model. On one hand, vocational colleges provide tiered and tailored training to enhance financial and managerial skills; on the other, digital platforms support systematic upgrades in asset management, production, and oversight.
Keywords: Vocational education; Rural governance; “Three resources” management; New agricultural business entities; Digital transformation

Digital Transformation and Strategic Management in Chinese Energy Enterprises’ International Operations
Yang Yuman, Xu Shaopu
School of Business, Geely University of China, Chengdu, Sichuan 641423
This study examines how digital platform architectures drive international competitive advantage for Chinese state-owned enterprises in Belt and Road Initiative markets (2020-2025). Analyzing 147 documents from State Grid, CNOOC, and Sinopec, it extends COBIT frameworks for state-controlled digital transformation. Findings reveal: State Grid’s smart grids achieved 3-4% transmission losses (vs. 8-10% standard) managing RMB 320B overseas assets; CNOOC’s AI model boosted offshore efficiency 30% across 20+ jurisdictions; Sinopec’s platform enabled RMB 92.4B B2B transactions with 95% automation. The research advances three theoretical constructs: (1) Dual Governance Integration Model balancing market efficiency with state mandates, (2) Cross-Border Digital Governance Framework for 51 jurisdictions, and (3) Platform Ecosystem Orchestration Model explaining state-backed network effects.
Keywords: state-owned enterprise digital transformation; platform ecosystem governance; Belt and Road Initiative energy infrastructure; artificial intelligence-enabled smart grids

Integrating Renewable Energy into Corporate Strategy: Evidence from Energy-Intensive Manufacturing Sectors
Lei Mei, Yang Yang
School of Business, Geely University of China, Chengdu, Sichuan, 641423
The transition toward low-carbon development has placed unprecedented pressure on energy-intensive manufacturing sectors to adopt renewable energy solutions. While technological adoption has been widely studied, less attention has been paid to how renewable energy integration into corporate strategy affects firm performance. This study investigates the strategic incorporation of renewable energy in energy-intensive manufacturing enterprises and its implications for financial and market outcomes. Using a panel dataset of 286 listed companies in the steel, cement, chemical, and paper industries from 2015 to 2024, we measure renewable energy adoption through the proportion of renewable energy in total consumption and assess strategic integration via content analysis of annual reports and sustainability disclosures. The results reveal that renewable energy adoption has a significant positive impact on both financial performance (ROA, ROE) and market valuation (Tobin’s Q), and that the degree of strategic integration strengthens this relationship.
Keywords: renewable energy adoption; corporate strategy; energy-intensive industries; firm performance; sustainability

Empirical Analysis of Influencing Factors on New Energy Vehicle Sales in Sichuan Province Using Hybrid Time-Series Models
Xieyu Chen
Geely University of China

Measurement and Evaluation of Green Development Efficiency in Sichuan Province Based on DEA-Malmquist Index Model
Liu Yue
Shengbao Fintech College, Geely University of China, Chengdu, Sichuan, 641423
This study employs the DEA-Malmquist index to evaluate green development efficiency in Sichuan Province, its four major economic zones, and 18 prefecture-level cities from 2014 to 2023. The results indicate that the overall green development efficiency in Sichuan Province has exhibited a gradual increase, although the growth rate is constrained. Technological efficiency improvements are the primary factor driving the enhancement of Sichuan’s green development efficiency, while insufficient technological progress has become a significant constraint. In the four economic zones, the green development efficiency demonstrates overall improvement, regional disparities and cyclical fluctuations, showing significant differences in efficiency levels and growth stability across areas. The spatial distribution of green development efficiency among 18 cities exhibits uneven distribution, forming distinct gradient patterns, with some cities facing challenges in green transition.
Keywords: DEA-Malmquist index model; green development efficiency; regional difference; Sichuan Province
10:15 — 10:45
Coffee Break
Potentially hazardous elements in environmental and food samples: Total content and speciation analysis
A. Gołębiowski¹,², R. Dzingelevičienė², B. Buszewski¹,²,
¹Prof. Jan Czochralski Kuyavian-Pomeranian Research and Technological Centre in Torun
²Faculty of Health Sciences, Klaipeda University
Potentially hazardous elements is a term used for describing a group of elements that may pose a hazard due to their toxic, mutagenic, and other properties towards living organisms and the environment. This group includes elements such as arsenic, mercury, lead, and cadmium. They are widespread in nature and can pose a risk to humans mainly through dietary intake – for example, by consuming food that contains trace amounts of these elements. However, the biological properties (toxicity and others) and physicochemical properties (solubility and others) of these elements depend strongly on their speciation forms in the samples. The presentation will show the results of studies on the development of methods for determining the total content of these elements in various environmental and biological samples (plants) and food (honey). The aim of the conditions selection procedure was to minimize the impact of spectral and non-spectral interferences observed during the determination of elements performed using inductively coupled plasma mass spectrometry (ICP-MS). Another main point of the presentation will be the presentation of research on determining the speciation forms of cadmium in plants and studies aimed at explaining the mechanisms by which plants reduce the toxic effects of cadmium.
Keywords: speciation analysis, potentially hazardous elements, food, plant

Heavy metals in fertilizers and food
N. Haneklaus
University of Vienna, Vienna, AT
Heavy metals, especially those introduced via phosphate-based mineral fertilizers, enter soils and can move along the soil–plant–food pathway. The presentation provides an overview of ongoing research of selected commercially available fertilizers in East Africa that show elevated uranium concentrations as well as alternative fertilizers that are presently being investigated for potential use in Europe.
Keywords: heavy metals, mineral fertilizers, uranium, food

How the pools of extractable plant nutrients (P and K) in soils are described by the Mehlich 3 method used for estimation of soil fertility status
Tõnu Tõnutare¹, Tõnis Tõnutare¹, Kadri Krebstein¹, Raimo Kõlli¹, Kersti Vennik²
¹Estonian University of Life Sciences, Tartu, EE
²Estonian Military Academy, Tartu, EE
To determine the pools of plant-available nutrients in soil the extraction methods are used. Many extraction methods have been developed over more than a century. Extraction methods can be divided to mono- and multielement methods depending their extraction ability. In Europe today at least 12 different methods are used only for determining plant-available P content. Typically for extraction of low-concentration salts, acids, or their mixtures water solutions are used. Depending on the solution composition, the amount of extractable nutrient may vary significantly. But not only the solution composition have influence to the amount of nutrient extracted from soil. Also the soil’s chemical and physical properties play a significant role in the quantity of extracted elements. These factors are not taken into account typically in making fertilization recommendations according to the results of plant nutrient analysis. This may cause environmental problems due to overfertilization as well as poor yields due to insufficient fertilization. In both cases, economic damage has been caused to the farmer. The presentation describes how different the soil plant nutrient real pools can be from the reported Mehlich 3 method analysis results.
Keywords: Soil fertility, plant nutrients, methods of soil analysis

Alternative plasticizers in protein supplements and their packaging — comparative studies using GC-MS/MS technique
M. Śmiełowska¹,², R. Dzingelevičienė², B. Buszewski¹,²
¹Prof. Jan Czochralski Kuyavian-Pomeranian Research and Technological Centre in Torun
²Faculty of Health Sciences, Klaipeda University
With the increasing replacement of phthalates in the packaging and food industries, the occurrence of so-called alternative plasticizers in consumer products has emerged as a critical issue. The objective of this study was to investigate the presence of selected alternative plasticizers—tributyl acetylcitrate (ATEC), diisobutyl adipate (DIBA), tributyl o-acetylcitrate (ATBC), dibutyl sebacate (DBS), bis(2-ethylhexyl) adipate (DEHA), trioctyl trimellitate (TOTM), and bis(2-ethylhexyl) terephthalate (DEHT)—in protein supplements for athletes and in their associated packaging materials. A selection of commercially available protein products, including powders and ready-to-drink formulations, as well as their packaging materials, were analyzed. Samples were extracted using the QuEChERS technique and subsequently examined by gas chromatography coupled with tandem mass spectrometry (GC-MS/MS) operated in multiple reaction monitoring (MRM) mode. Preliminary findings demonstrate the occurrence of several of the investigated plasticizers in both the supplements and their packaging, suggesting potential migration from packaging materials into the food matrices. These results underscore the necessity of further investigations into the migration behavior of alternative plasticizers into dietary supplements, particularly given the growing popularity of these products and the limited regulatory framework governing permissible additives in packaging materials.
Keywords: alternative plasticizers (APs), migration potential, food safety, exposure assessment, food contact materials
Climate Change Impacts on Water-Energy-Food Nexus: Pathways to Resilience and Sustainability
Prof. Majeti Narasimha Vara Prasad
Retired Professor, University of Hyderabad, Hyderabad 500046, Telangana, India
Sustainable and equitable utilization of natural resources without exceeding the Planetary boundaries is imperative to one and all as envisioned in the UN-SDGs. With rapid urbanization, cities are main human settlements so that adaptation for climate-resilient and livable cities is an important theme with considerations of Good Health and Well-being (SDG# 3), Quality Education in sustainability Science (SDG#4), Sustainable Cities and Communities (SDG#11) and Climate Actions (SDG#13) under the UN Sustainable Development Goals. A decade of weather extremes as reported in Nature climate change by Coumou and Rahmstorf, as early as in 2012 are due to climate change. The Earth’s climate is changing and now it stands at a position of 1.0-1.1ºC above pre-industrial level. Climate change has already caused significant environmental, economic and social consequences, among which impacts on human health, safety and societal security are prominent. Unfortunately, the society has not well prepared to act for adaptation due to limited understanding of impacts of climate change on human health and safety, weak awareness and knowledge of climate-induced risks, vulnerabilities and solutions, lacking climate-related health guidelines and regulations, insufficient education, finance and advocacy of climate change adaptation, and slow actions for climate adaptation transformation in the nexus of water, energy, and food.
Keywords: climate change, water-energy-food nexus, resilience, sustainability, planetary boundaries, UN-SDGs, climate adaptation
The Effect of Wildflower Gardens on Biodiversity
Ágnes Bálint¹, Lakatos Balázs¹, Xuechu Wang², Csaba Mészáros²
¹Óbuda University, 1034 Budapest, Hungary
²Hungarian University of Agriculture and Life Sciences, 2100 Gödöllő, Hungary
The aim of the research is to examine the extent to which wildflower gardens can contribute to increasing local biodiversity, particularly with regard to the presence and activity of pollinators and other insects. The work was carried out in a spontaneously formed wildflower garden in Solymár, Hungary, which had not been mowed regularly for five years and had experienced minimal human intervention. The study covered four areas with different characteristics, and a traditional, regularly maintained lawn garden served as a control. During the research, we used field plant surveys, traps, and field insect observations. We used the Shannon index to determine species richness and evenness in the plant surveys, while insects were mainly evaluated based on relative abundance. The studies lasted from February to the end of April. The diversity of plant species varied significantly between the different areas: it was lower in the shady, densely vegetated area (H=1.56), while it was particularly high in the sunny, meadow-like area (H=2.64). In contrast, the control garden was significantly poorer in species, mainly characterised by grasses and a few planted ornamental plants. In the wildflower garden, protected plant species that had settled naturally were also identified (e.g., snowdrop, narrow-leaved lungwort, strawberry), which is also valuable from a nature conservation perspective. The most common pollinators were wild bees, domestic bees, and hoverflies. The density and species richness of flowering plants clearly influenced their presence: significantly more pollinators were observed in sunny, flower-rich areas than in the control garden. In addition to these, there were also large numbers of ground-dwelling and nocturnal beetles. Finally, the soil of the wildflower garden showed better ecological status than the control area in terms of organic matter content (6.7%), carbon (3.82%), nitrate (46.25 mg/kg), phosphate (2.73 mg/kg), and ammonium content (25.32 mg/kg) than the control area, where these values were lower. The results of the biomass measurement also demonstrated the superiority of the wildflower garden, with more than nine times as much plant material collected here as in the control area. Based on these findings, the primary conclusion of the research is that even a medium-sized, naturally developing garden can make a significant contribution to increasing local biodiversity, especially when managed with minimal intervention. Wildflower gardens are not only refuges for pollinators, but also have a beneficial effect on soil water management, microclimate regulation, and, in the long term, the mitigation of climate change. It is recommended to encourage the spread of such gardens, even on smaller urban plots, balconies, or institutional green spaces.
Keywords: wildflower gardens, biodiversity, pollinators, urban ecology, Shannon index, species richness
Purification of concentrate containing organic contaminants from membrane processes using advanced oxidation
Marta Iwona Bolińska*¹, Janina Piekutin², Urszula Kotowska³
¹,²Department of Technology in Environmental Engineering, Bialystok University of Technology, 45A Wiejska Street, 15-351 Bialystok, Poland
³Department of Analytical and Inorganic Chemistry, University of Bialystok, Ciołkowskiego 1K Street, 15-328 Bialystok, Poland
The aquatic environment is experiencing an increasing amount of endocrine-disrupting organic pollutants originating from everyday personal care products. As a result of inadequate treatment of raw sewage using conventional biological methods, these pollutants enter the aquatic environment and then migrate up the food chain. Studies show that membrane methods, such as nanofiltration and reverse osmosis, allow for the effective separation of these substances from water, but this involves the formation of a concentrated retentate. This concentrate contains high concentrations of pollutants separated on the membrane, thus creating a highly toxic and dangerous mixture that must be properly managed so that it does not pose a threat to the environment. Laboratory tests were undertaken to dispose of the concentrate obtained. The advanced oxidation processes (AOPs) used, based on peracetic acid (PAA), exhibit good oxidizing potential and effectively purifying the concentrate after membrane processes.
Keywords: membrane processes, oxidation, retentate, PAA
Acknowledgement: The project was financed in the framework of the Bialystok University of Technology program “Projekt PhD” (No: WI/WB-IIŚ/19/2025).

Reaction mechanism of sulfate radical-based advanced oxidation processes in various matrices
Klaudia Raczak, Stanisław Wacławek
Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, 461 17, Liberec, Czech Republic
Advanced oxidation processes based on sulfate radicals (SR-AOPs) are a promising method for degrading organic pollutants in water and disintegrating waste-activated sludge (WAS). Sulfate radicals can be efficiently generated by activating peroxymonosulfate (PMS) or peroxydisulfate (PDS) via physical methods (heat, UV, ultrasound) or chemical methods (transition metals, electrolytic, carbon-based materials). While many studies have demonstrated their efficiency in degrading organics, the exact reaction mechanisms and applicability in wastewater treatment plants (WWTPs) require further investigation. This study introduced, for the first time, nano zero-valent iron (nZVI) coated with silver or copper to activate PDS in WAS, addressing challenges in sludge disintegration and volume reduction. Fourier transform infrared spectroscopy (FTIR) was used to study WAS dehydration and better understand the SR-AOP mechanism. Moreover, various persulfate activation methods were compared, including UV-Vis irradiation with four different lamps (TQ-150, HG-Z1, HG-Z2, HG-Z3), and degradation of the model compound Acid Blue 129 was evaluated via kinetic rate constants. Four previously unrecognized reaction by-products were also identified, providing further insight into SR-AOP mechanisms. Overall, this work advances understanding of SR-AOPs for degrading organic substances in complex matrices and supports the development of sustainable water treatment strategies applicable at large scale.
Keywords: sulfate radicals, advanced oxidation processes, peroxydisulfate, peroxymonosulfate, waste-activated sludge, nano zero-valent iron, wastewater treatment, sludge disintegration, persulfate activation, reaction mechanisms

Adsorption of chlorinated solvent vapors Using Graphene Derivatives
Masoud Khaleghiabbasabadi¹,², Clarissa Settimi³, Daniele Silvestri*¹, Miroslav Černík¹,², Daniela Zingaretti³, Stanisław Wacławek¹,², Iason Verginelli*³
¹Institute for Nanomaterials, Advanced Technology and Innovation, Technical University of Liberec, 46001, Liberec, Czech Republic
²Faculty of Mechatronics, Informatics, and Interdisciplinary Studies, Technical University of Liberec, 46001, Liberec, Czech Republic
³Department of Civil Engineering and Computer Science Engineering, University of Rome Tor Vergata, Via Del Politecnico 1, 00133, Rome, Italy
This work explores the innovative use of green-fabricated graphene derivatives as sorbents for the passive remediation of chlorinated solvent vapors. Reduced graphene oxide (rGO), electrochemical graphene oxide (EGO), and nitrogen/sulfur co-doped graphene oxide (NSGO) were produced via electrochemical exfoliation, providing a more sustainable approach than conventional synthesis routes. Comprehensive characterization techniques (SEM-EDX, Raman, XRD, and TGA) verified the successful fabrication of graphene derivatives with distinct surface features, including oxygen functionalities and heteroatom incorporation in NSGO. Batch adsorption tests using trichloroethylene (TCE) as a model contaminant demonstrated strong vapor uptake capacities for rGO, EGO, and NSGO, with NSGO (159 mg g⁻¹) showing the highest adsorption performance. The enhanced efficiency of NSGO was linked to its higher oxygen content and the synergistic influence of nitrogen and sulfur dopants, which provided additional active sites and improved electronic interactions. Isotherm analysis showed that the Brunauer–Emmett–Teller (BET) model most accurately described the data, indicating a multilayer physisorption process governed by van der Waals forces, hydrogen bonding, and π–π interactions. Compared with conventional carbon-based sorbents, these graphene derivatives offer competitive adsorption capacity while eliminating the use of hazardous chemicals and supporting scalable production.
Keywords: Graphene derivatives; Chlorinated solvent, Reduced graphene oxide (rGO), Trichloroethylene, Vapor-phase adsorption, Electrochemical graphene oxide (EGO)
13:00 — 14:00
Lunch
A Regional Bioeconomy Network — Challenges and Solutions in the Lusatian Area
Prof. Jens Weber
Hochschule Zittau/Görlitz, DE
This presentation will report on the creation of a regional bioeconomy network in the Lusatian Area, starting from 2017 up to today. The establishment of a vibrant network, regionally anchored in Lusatia, focusing on holistic material and technology development around natural fiber-reinforced plastics (NFRPs) is the overarching goal of the so-called LaNDER³ partnership. Natural fibres, (bio)polymers, circular economy and renewable energies — that’s where we see innovation potential. The partnership is based at the Zittau/Görlitz University of Applied Sciences (HSZG) and is strengthened by cooperation with companies and partners. It brings together technical expertise, connects stakeholders from business, science, and society, explores and develops new approaches, and thus provides impetus for the region. The momentum created by funding from the Federal Ministry of Education and Research (BMBF) and partners from industry can lead to effective results in the medium and long term. Our activities have two overarching strategic goals: The first, to some degree intrinsic objective is to build up a regionally active, self-sustaining network: Companies and stakeholders alike are involved in the various sub-projects according to their capabilities in order to provide impetus for the economy of the Upper Lusatia region. The second, extrinsic goal is to provide answers to the challenges of structural change. Examples include Germany’s Energiewende (‘energy transition’) and the associated disruptions (decline in lignite production in Lusatia and the associated industries) as well as the ongoing and visible demographic change in the region. High levels of innovation and transfer capabilities in business and science are essential for the upcoming structural change. The locally strong polymer processing industry can provide a good basis for this. The development of technology related to NFRPs should therefore also form a basis for the further development of industry and related sectors (e.g., suppliers, tool manufacturers, fiber producers/agriculture) to key positions in a future “post-lignite” economic area. Following this vision, we used the first years to build up the new network, anchor it locally and supraregionally and to raise its profile. We will report on our learnings to date and our connections to the Water-Energy-Food nexus.
Keywords: bioeconomy, regional networks, Lusatian area, sustainability, natural fiber-reinforced plastics, circular economy, structural change
Magical Mercury – Live Chemistry Show
Dr. Zbigniew A. Szydło
Highgate School, London, UK
The aim of the talk is to show that mercury is one of the most important substances known to Man. Out of the seven metals known in Ancient times, mercury held the greatest fascination. This was on account of its liquid state, high density and beautiful shiny silver lustre. It has probably been known and extracted from its ore cinnabar [mercuric sulphide] for some 3000 years. Mercury was accorded a place among the Gods in Roman mythology, having figured as Hermes in Greek mythology. For many centuries, mercury and its compounds featured in a wide variety of medical applications and was considered by Chinese philosophers to be associated with eternal life. From about 300 BC the alchemical philosophy underpinned Man’s understanding of matter. Its main tenets were Aristotle’s ideas of the four elements [earth, air, fire and water], the concept of transmutation which explained all changes, and a firm belief that matter is continuous and thus cannot tolerate a vacuum. Mercury featured in the Arabic sulphur-mercury theory of metals, which was a cornerstone of alchemical philosophy from about 800 AD until the 17th century. During the 17th century, mercury started to acquire a new significance. It was used in scientific experiments. One of these was conducted in 1643 by the Italian physicist Torricelli [1608-1647], who used it to demonstrate the existence of a vacuum. The consequences of Torricelli’s experiment were colossal, and long lasting. It led to the ground breaking re-interpretation of the nature of matter, which was from then understood to be particulate, and not continuous. Fire has played a most important role in human history. One of the greatest mysteries of the natural world was the phenomenon of burning, or combustion. How and why do fires burn? This topic had consumed an enormous amount of writing, speculation and experiments over a period of some 2000 years. In 1787, the French chemist Lavoisier [1743-1794] used the calx of mercury to finally solve the mystery of combustion — he recognised that when fires burn, the fuel enters into a chemical combination with oxygen, resulting in the formation of new substances. Lavoisier’s work laid the foundations of modern chemistry. This in turn, played a key role in the Industrial Revolution, and continues to underpin modern technological society. The electric motor is one of the most ubiquitous machines in use today. It was invented by Faraday [1791-1867] in 1823. Faraday used mercury in his first electric motor which utilised the newly discovered (by Oersted [1777-1851] in 1820) phenomenon of electromagnetism. Mercury is element no. 80 in the Periodic Table, and is a d block element. Its most interesting chemical and physical properties will be demonstrated in a series of laboratory experiments.
Keywords: mercury, alchemy, chemistry, experiment, historical chemistry, scientific demonstrations
15:00 — 15:15
Concluding of the Conference and Award ceremony
Organising Committee
Poster Session
Poster boards displayed throughout October 23–24
Dedicated discussion session: October 24, during Young Researchers Forum
EMS as a Tool in Environmental Engineering
M. Piekarski, K. Grübel
University of Bielsko-Biala, Bielsko-Biała, PL
This article presents an assessment of energy efficiency and Energy Management System (EMS) practices in the automotive sector in the Silesian Voivodeship, Poland. This was achieved by: 1. Determining the prevalence of monitoring, sub-metering, energy efficiency indicators (ENPI), audits, and efficiency measures. 2. Assessing the gaps between declared policies and actual practice. To examine how companies manage energy in practice, this study utilized a structured survey addressed to automotive manufacturers in the Silesian Voivodeship. None of the surveyed companies reported quantitative results, such as energy savings or financial returns. Furthermore, none had a formal EMS or ISO 50001 certification. The survey shows that energy initiatives are often tactical in nature, driven by current needs rather than long-term strategy – especially in the case of SMEs, where technical and financial barriers persist.
Keywords: energy management systems (EMS), ISO 50001, automotive sector, energy performance indicators (EnPIs)
Metal Recovery from E-Waste: Combination of Hydrometallurgy and Membrane Extraction
A. Kadlecova, V. Durdak, J. Krouzek
University of Chemistry and Technology, Prague, CZ
The escalating demand for critical raw materials and the legislative objectives of the European Union (e.g. the Critical Raw Materials Act) highlight the need to increase self-sufficiency in strategic metals. Recycling of metals from waste materials, especially e-waste, is a key route to sustainable availability and reduction of the environmental impacts of primary mining. However, effective separation of target elements from complex matrices is a major challenge. This study investigated hydrometallurgical processes for the recovery of valuable metals (cobalt, lithium, nickel, copper, manganese) from the waste dust from e-waste recycling facility. For the sample of this currently valueless waste, we applied acidic leaching followed by non-dispersive membrane extraction for selective metal separation. Factors such as the composition and concentration of the leaching solution, duration of the process, and temperature were systematically investigated. Various extractants (TBP, Cyanex 272, D2EHPA) with appropriate additives, were evaluated for the extraction phase. Resulting aqueous solutions were analyzed using microwave plasma Atomic Emission Spectrometry (MP AES). The experimental results confirmed that the selection of optimal leaching solutions significantly affects the metal recovery. The non-dispersive membrane extraction technology demonstrated high selectivity and efficiency in the extraction of selected elements, suggesting its potential for further optimization leading to increased purity of extracted components and reduced energy consumption. The study demonstrates that the combination of hydrometallurgical methods and membrane extraction is an innovative, efficient and environmentally friendly approach to recycling critical metals from waste materials, with potential for wider industrial use in other applications. Further research will focus on optimization of process parameters and economic efficiency.
Keywords: hydrometallurgy, e-waste, membrane extraction, metal recovery
Comparison of Co-Digestion of By-Products After Biodiesel Production and Effective Membrane Treatment of Post-Digestion Liquors
M. Kuglarz, K. Grübel
University of Bielsko-Biala, Bielsko-Biała, PL
The aim of this study was to develop the technological concept ensuring: (1) high efficiency co-digestion of by-products from the production of biodiesel and sewage sludge as well as (2) an effective method of post-digestion effluents treatment, – to the level allowing its discharge to the natural reservoir.
Keywords: co-digestion, biogas, biodiesel, sewage sludge
Alginate-Based Composites with Added Graphene Oxide Formed In Situ for Heavy Metal Removal
Ł. Migdał, B. Fryczkowska, P. Zaręba
University of Bielsko-Biala, Bielsko-Biała, PL
Industrial wastewater containing heavy metals such as zinc, copper, lead, chromium, nickel, cadmium, arsenic, cobalt and mercury is one of the types of wastewater that negatively affects the environment. Various types of sorbents can be used to remove metal ions. An interesting solution is sorbents based on polysaccharides. The paper presents research on the production and application of granules based on 2 % alginate (ALG) with the addition of 2.81 % graphene oxide (GO) as sorbents for ions: Ni²⁺, Co²⁺, Cu²⁺, Pb²⁺, Cd²⁺. For the research, GO/ALG solutions were prepared, which contained from 0.18 % to 5.62 % of GO additive. The granules were formed by direct introduction of alginate solutions to solutions containing metal ions. It was observed that the use of the in situ formed sorbent allows for the removal of all tested metal ions, in amounts from 5 % (Cd²⁺) to 25 % (Co²⁺).
Keywords: alginate, graphene oxide, composites, heavy metals
PFAS under Surveillance: Scheduled MRM and Isotopically Labeled Standards in Wastewater Analysis
M. Zarębska¹,², S. Bajkacz², K. Malorna¹
¹Łukasiewicz Research Network- Institute of Heavy Organic Synthesis “Blachownia”, Kędzierzyn-Koźle, PL
²Silesian University of Technology, Faculty of Chemistry, Department of Inorganic, Analytical Chemistry and Electrochemistry, Gliwice, PL
Poly- and perfluoroalkyl substances (PFAS) are persistent environmental contaminants that pose a serious threat to aquatic ecosystems and human health due to their high stability and potential toxicity. Their widespread presence in wastewater and surface waters, combined with the limited removal efficiency of conventional treatment technologies, highlights the need for sensitive and reliable analytical methods. The aim of this study was to develop and validate a method for the determination of selected PFAS in aqueous matrices and to assess its compliance with green analytical chemistry (GAC) principles. A method based on solid-phase extraction (SPE) coupled with liquid chromatography–tandem mass spectrometry (LC-MS/MS) using scheduled multiple reaction monitoring (sMRM) and 18 isotopically labeled internal standards was applied. The method achieved limits of detection (LOD) ranging from 0.03 to 1.42 ng/L and limits of quantification (LOQ) from 0.11 to 4.73 ng/L. Recovery rates ranged from 74.9% to 118%, with precision (RSD) between 5.3% and 20.0%, confirming its suitability for the analysis of wastewater samples. The method was also used to evaluate the removal efficiency of selected wastewater treatment plants by comparing PFAS concentrations in influent and effluent samples, providing insight into their fate during treatment processes. Evaluation of method greenness resulted in the following scores: AGREE — 0.55, MoGAPI — 64%, AGSA — 62%, and CACI — 59 points, indicating moderate compliance with GAC principles across all applied metrics. The developed method allows for accurate and sensitive determination of PFAS in environmental water samples and may serve as a valuable tool for routine wastewater monitoring.
Keywords: PFAS, wastewater analysis, LC-MS/MS, green analytical chemistry, method validation
Advanced Reductive Processes (ARP) as an Effective Tool for PFAS Photodegradation in Wastewater
M. Zarębska¹,², S. Bajkacz², E. Felis³, P. Sowik³, A. Bluszcz⁴
¹Łukasiewicz Research Network- Institute of Heavy Organic Synthesis “Blachownia”, Kędzierzyn-Koźle, PL
²Silesian University of Technology, Faculty of Chemistry, Department of Inorganic, Analytical Chemistry and Electrochemistry, Gliwice, PL
³Silesian University of Technology, Biotechnology Centre, Gliwice, PL
⁴Silesian University of Technology, Faculty of Energy and Environmental Engineering, Department of Water and Wastewater Engineering, Gliwice, PL
The global prevalence of poly- and perfluoroalkyl substances (PFAS) raises serious concerns due to their bioaccumulation potential, environmental persistence, and possible ecotoxicological effects. In the search for safer alternatives, replacements for traditional PFAS have been developed, including the ammonium salt of hexafluoropropylene oxide dimer acid, commercially known as GenX. Although initially considered less harmful, GenX has shown high resistance to biodegradation and potential toxicity, prompting concerns about its environmental and public health impacts. Moreover, conventional water treatment methods have proven largely ineffective in removing this alternative PFAS. In recent years, growing interest has emerged in Advanced Reduction Processes (ARPs), which offer a promising strategy for PFAS degradation. These technologies, supported by ultraviolet (UV) irradiation, employ sensitizers to generate strongly reducing hydrated electrons (eaq⁻), capable of cleaving stable C–F bonds. The aim of this study was to assess the synergistic effect of sensitizers in a UV/sulfite/iodide system as an innovative strategy for GenX remediation. Specifically, the research focused on comparing GenX degradation efficiency in single and combined systems, optimizing sulfite and iodide ratios and concentrations, analyzing the influence of key reaction parameters such as pH and initial GenX concentration, determining reaction kinetics, evaluating the effectiveness of the developed ARP system in various types of wastewater, and investigating the degradation mechanism of GenX, including identification of major transformation products. The results demonstrate that UV-activated systems using iodide and sulfite at optimized pH conditions provide an effective and energy-efficient strategy for GenX degradation. Through the generation of hydrated electrons, both traditional and alternative PFAS can be efficiently removed from wastewater, offering new prospects for advanced remediation technologies targeting fluorinated organic contaminants.
Keywords: PFAS, GenX, photodegradation, advanced reduction processes, ARP, hydrated electron
Simulation of Lithium-ion Battery Thermal Management with PCM Materials: An Eco-Techno-Environmental Analysis
A. Ahmadi¹, S. Naderi¹, D. Silvestri¹, S. Wacławek¹, M. Černík¹, K. Behzadian², M. Gheibi¹*
¹Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, 461 17, Liberec, Czech Republic
²School of Computing and Engineering, University of West London, London, UK
Thermal management remains one of the most persistent challenges in advancing lithium-ion batteries (LIBs), particularly as demand for high-energy storage technologies expands across transportation, grid systems, and portable devices. Excessive heat generation not only accelerates material degradation but also threatens operational safety, underscoring the need for reliable regulation methods. While conventional cooling strategies have been widely adopted, recent scholarship has questioned their ability to balance technical performance with environmental and economic sustainability. Within this debate, phase change materials (PCMs) have emerged as promising alternatives, yet systematic investigations that combine simulation, optimization, and predictive modeling remain limited. Addressing this gap, the present study evaluates five distinct PCMs using a multi-method framework. Computational analyses conducted in ANSYS 2021 R2 examined each PCM’s capacity to mitigate temperature rise and ensure uniform heat dissipation. Response Surface Methodology (RSM) was then employed to optimize operating conditions, and machine learning techniques were applied to predict battery behavior under varying scenarios. Results indicate that PCMs can reduce maximum temperature by approximately three percent relative to baseline, with metal-based PCMs exhibiting stronger thermal stability (302 K, 48.41 W·m⁻² heat flux). Sensitivity analysis identified thermal conductivity, density, and viscosity as the most critical properties influencing system performance. By integrating computational, statistical, and data-driven approaches, this research provides a more comprehensive evaluation of PCMs than previous studies, while also situating thermal management within techno-economic and environmental frameworks. In doing so, it advances current debates on sustainable energy storage and contributes to the development of battery systems aligned with the Sustainable Development Goals (SDGs).
Keywords: Battery; Thermal Analysis; Phase Change Materials; ANSYS; Optimization; Machine Learning
Sulfate radical-mediated degradation of vancomycin: Kinetics, mechanism, and toxicity evaluation
K.B. Raczak¹, D. Silvestri¹*, M. Salava¹, M. Černík¹, S. Wacławek¹
¹Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, 461 17 Liberec 1, Czech Republic
Sulfate radical-based processes (SRPs) are promising water remediation techniques with the potential to outperform traditional oxidation methods in various water matrices. This study investigates vancomycin (VAN) degradation, an organic micropollutant in water, using thermally activated persulfate. Through competition kinetics, the second-order reaction rate constant between sulfate radicals (SO4●–) and VAN was determined to be 3.4 × 10⁸ M⁻¹ s⁻¹. The degradation of VAN was influenced by various conditions, including acidic and alkaline pH, and the presence of natural water components such as bicarbonate, chloride and humic acid. However, VAN was fully degraded in less than one hour under all conditions tested. Moreover, an oxidation by-product, identified as acetylated VAN, was predicted through quantum chemical calculations and confirmed via HPLC-qTOF-HRMS analysis. Furthermore, toxicity tests using Algaltoxkit F® demonstrated that the by-product was significantly less toxic to the algae Selenastrum capricornutum. In conclusion, the reaction between sulfate radicals and VAN occurs rapidly (3.4 × 10⁸ M⁻¹ s⁻¹). Since SO4●– strongly prefers electron-rich sites, it is highly efficient in eliminating VAN in a wide range of environmental matrices.
Keywords: glycopeptide antibiotic; micropollutants; peroxydisulfate; SR-AOP; water treatment
Electrokinetic Remediation of Heavy Metals in Mining Sludge: Mechanisms, Efficiency, and Case Study from Zlaté Hory
Z. Hajiahmadi¹, M. Gheibi¹, D. Silvestri¹*, M. Černík¹, S. Wacławek¹*
¹Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, Liberec, 461 17, Czech Republic
Electrokinetic remediation is an emerging technology for the treatment of heavy-metal-contaminated sludge and soils, offering sustainable solutions for both risk management and resource recovery. This study investigates the electrokinetic removal of zinc (Zn²⁺) from sludge generated at the Zlaté Hory mine site in the Czech Republic. Laboratory-scale experiments were conducted using a semi-saturated sludge–sand matrix exposed to an applied electric field of 1–2 V/cm for 17 days. The results demonstrate that electric field-driven processes, including electro-osmosis, electrophoresis, and electrolysis, dominated over diffusion in mobilizing and transporting Zn²⁺ toward central and electrode zones. Zinc accumulation exceeded 5 mg/L, with effective migration pathways confirmed through spatial mapping. The findings highlight the efficiency of electrokinetic remediation in low-permeability substrates, minimizing ecological disturbance while enabling selective recovery of valuable metals. Compared to conventional excavation-based techniques, electrokinetics preserves soil structure and reduces secondary waste generation, making it a promising method for the sustainable management of contaminated mining residues.
Keywords: Electrokinetic remediation; heavy metals; sludge treatment; zinc removal; electro-osmosis; electrophoresis; electrolysis; mining waste; risk management; resource recovery; Zlaté Hory mine
Intelligent Optimization of Heavy Metal Adsorption onto LDC Wastes
M. Gheibi¹, M. Palušák¹, D. Silvestri¹*, M. Černík¹, S. Wacławek¹*
¹Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, Liberec, 461 17, Czech Republic
This study examines the adsorption of Pb²⁺, Mn²⁺, and Co²⁺ ions onto low-density concrete (LDC) wastes as a sustainable approach for heavy metal removal from water. Response Surface Methodology (RSM) was used to identify pH, adsorbent mass, and contact time as key factors, with pH around 5 providing optimal efficiency. Experimental results showed the highest affinity for Pb²⁺, while Co²⁺ reached removal efficiencies up to 99%. Machine learning models, particularly Random Forest (TRF), demonstrated strong predictive capability with correlation coefficients approaching 0.99. The integration of RSM and ML provides a reliable framework for process optimization and intelligent decision-making in water treatment applications.
Keywords: Heavy metal removal; adsorption; low-density concrete; RSM; machine learning; Random Forest
Pesticide residues in selected vegetables “under the microscope”
Radosław Lewiński¹, Wojciech Korcz¹, Katarzyna Czaja¹, Monika Liszewska¹, Paweł Struciński¹
¹Department of Toxicology and Health Risk Assessment, National Institute of Public Health NIH – National Research Institute, 24 Chocimska, 00-791 Warsaw, Poland
The consequence of using plant protection products in agriculture is the presence of pesticide residues in food. Monitoring their levels in foodstuffs is one of the key elements of the food safety policy in the European Union. This study covers results of pesticide residue analysis in 3,313 samples of selected vegetables (potatoes, celeriacs, head cabbages, Chinese cabbages, broccoli, carrots, cucumbers, sweet peppers, parsley roots, tomatoes, leeks, lettuces) grown in Poland, obtained in frame of official food control in 2017-2022. Among this pool of food, in 1,552 samples (46.8%) no pesticide residues were quantified. 1,434 samples (43.3%) contained residues of at least one pesticide within legal limits. A total of 327 samples (9.9%) exceeded legal limits, of which 211 samples (6.4%) were found to be non-compliant with the applicable MRLs. Boscalid, azoxystrobin, and difenoconazole were the most frequently determined active substances. Acute and chronic exposures were estimated for children and adults using the EFSA PRIMo rev 3.1 model. The health risk was characterised by referring the estimated intake of a given residue to the appropriate toxicological reference value (ADI, ARfD). All found chronic exposure values did not exceed 1% of the ADIs. Acute exposure was assessed for all non-compliances with MRLs, and chronic exposure was assessed for pesticide/vegetable combinations in which given pesticide was quantified in at least 25% of the samples. A significant part of the identified MRL non-compliances is attributed to the use of pesticides that have been withdrawn from use in the EU; some can also be linked with failure to comply with authorized good agricultural practices. Since MRLs are not toxicological endpoint values, their violation is not directly equivalent to health risk. However, some of non-compliances were assessed as potentially posing a threat to consumers’ health.
Keywords: vegetables, pesticide residues, risk assessment, food safety
Acknowledgement: Funding for this project was provided under FT-1.2025 by National Institute of Public Health NIH – National Research Institute.
The Role of Photovoltaics in the Green Transition: Environmental Advantages and Critical Element Challenges
J. Czupioł, G. Yandem, M. Pająk, A. Dzieniszewska, M. Jabłońska-Czapla
Institute of Environmental Engineering Polish Academy of Sciences, Zabrze, PL
Photovoltaics constitute one of the key pillars of the energy transition aimed at achieving climate neutrality. Thanks to the rapid development of PV technologies and the decreasing costs of their production, their widespread integration with urban and industrial infrastructure is becoming increasingly feasible. From an environmental perspective, photovoltaic systems offer a range of benefits: significant reduction of greenhouse gas emissions over the installation’s life cycle, no air pollutant emissions during operation, and low water consumption compared to conventional energy sources. Their implementation contributes to improved air quality in cities and enhances the energy resilience of local communities. However, the expansion of PV technology is accompanied by a growing demand for critical elements such as indium, tellurium, and gallium, whose limited availability and recycling challenges may pose a significant risk to the sustainable development of this sector. The constrained supply of these materials, their geographically concentrated occurrence, and low recycling efficiency could lead to energy dependence and generate new geopolitical tensions. Moreover, the lack of coherent strategies for PV waste management and the insufficient development of secondary material recovery technologies increase environmental pressure related to the end-of-life stage of these systems. Our aim is to highlight the dual nature of photovoltaic development in the context of the green transition: on one hand—as a technology with tremendous environmental potential, and on the other—as a source of new challenges in sustainable resource management. We place particular emphasis on the need to implement circular economy strategies, develop alternative semiconductor materials, and establish regulations supporting the recycling and recovery of critical elements. The sustainable development of photovoltaics requires not only technological innovation but also a systemic approach that considers the entire life cycle of PV installations and their impact on the environment and resource economy. The full potential of photovoltaics in the green transition can only be realized by simultaneously addressing both environmental and material aspects.
Keywords: Photovoltaics, Technology Critical Elements, Green transition, Circular economy, Sustainable resource management, Environmental impact
Acknowledgement: The research was carried out in the frame of project which received funding from the National Science Centre of Poland on the basis of the decision number UMO-2024/53/B/ST10/00619.
Degradation of microplastics with the use of peroxyacids and peroxysalts
Patrycja Zawiślak¹, Izabela Ryza¹, Joanna Karpińska², Justyna Kapelewska², Urszula Kotowska²
¹Doctoral School, University of Bialystok, Ciolkowskiego 1K, 15-245 Bialystok, Poland
²Laboratory of Environmental Chemistry, Faculty of Chemistry, University of Bialystok, Ciolkowskiego 1K, 15-245 Bialystok, Poland
Microplastics (MPs), a ubiquitous pollutant in the aquatic environment, pose a serious ecological and health threat. Their strong propensity to adsorb organic contaminants increases the risk of toxin transfer across the food chain, while potential long-term impacts in humans include effects on the circulatory, digestive, endocrine and nervous systems. Conventional wastewater treatment is not always able to retain all plastic particles, allowing MPs to enter surface waters and soils with effluents. This work investigates the modification of selected polymer microparticles using advanced oxidation processes (AOPs) with peroxyacetic acid and sodium percarbonate as oxidants. Both treatments rendered the microplastic surface more porous and hydrophilic, and FT-IR spectra confirmed the appearance of new functional groups, indicating pathways toward enhanced degradability and/or subsequent biodegradation.
Keywords: Advanced oxidation processes; peroxyacetic acid; sodium percarbonate; surface modification
Study of the variability of chlorophyll α content in the Goczałkowice reservior
J. Smoter, E. Jachniak
University of Bielsko-Biala, Faculty of Materials, Civil and Environmental Engineering, Bielsko-Biała, PL
The Goczałkowice reservoir plays a key role in supplying drinking and industrial water to many towns in Upper Silesia. The Vistula River, which feeds the reservoir, flows through spa and recreation centers, as well as industrial areas, collecting various nutrient-rich pollutants. One of the most important aspects of assessing the water quality of retention reservoirs is assessing their trophic status, which determines the level of eutrophication. This process impacts the ecological conditions and biodiversity of the aquatic ecosystem through excessive nutrient supply. Eutrophication leads to increased phytoplankton growth, which is manifested by increased chlorophyll α concentration in the water. Phytoplankton causes filter clogging, and the increased presence of microorganisms leads to changes in organoleptic properties and increases the cost of treatment processes. This paper presents an assessment of the trophic status of the Goczałkowice reservoir based on analysis of chlorophyll α concentration and selected physicochemical parameters. As an indicator of eutrophication levels, chlorophyll α allows for the determination of the growth intensity of planktonic algae and vegetation in the reservoir. Additionally, the analysis can contribute to a better understanding of the impact of external factors, such as meteorological conditions and anthropogenic factors, on water quality. The study results can provide valuable input for further actions aimed at improving water quality in the Goczałkowice reservoir.
Keywords: Water, chlorophyll a, trophic status
Surface water classification by unsupervised and supervised machine learning methods exploring multidimensional signals obtained with gas sensors
Magdalena Piłat-Rożek¹, Grzegorz Łagód²
¹Department of Applied Mathematics, Faculty of Mathematics and Information Technology, Lublin University of Technology, Nadbystrzycka 38, 20-618 Lublin, Poland
²Department of Water Supply and Wastewater Disposal, Faculty of Environmental Engineering and Energy, Lublin University of Technology, Nadbystrzycka 40B, 20-618 Lublin, Poland
In this study, machine learning models were applied to analyze multidimensional data obtained by matrix of gas sensors, concerning surface water of different quality – originating from drainage system, stormwater system as well as river. The aim of this paper was to compare the application superimposed with machine learning methods, on data from different sampling points. The performance of the mentioned methods, both supervised and unsupervised, was much higher for the data from the more polluted samples. With the algorithms, a clear clustering of the data was observed already with the unsupervised methods alone, while the supervised algorithms classified the observations into the corresponding class of quality (with reference to classical pollution indices evaluated by standard laboratory procedures) on the training and test sets. The application of the selected unsupervised methods to the drainage and river water data did not allow the clear separation of distinct groups for all observations. Nevertheless, the supervised methods showed greater potential for drawing conclusions – the vast majority of observations were classified into the correct location in the drainage, stormwater or river. However, the accuracy of the supervised models trained for data from stormwater system is higher than for those from drainages and river.
Keywords: surface water, stormwater, multidimensional data analysis, machine learning, gas sensors array
ISO 22000 Standard as a Tool for Ensuring Safety of Water Production in a Water Producing Company – AQUA Bielsko-Biala (Poland)
Magdalena Kóska-Wolny¹, Arkadiusz Kocot¹, Klaudiusz Grübel²
¹AQUA S.A., Bielsko-Biala, PL
²University of Bielsko-Biala, Faculty of Materials, Civil and Environmental Engineering, Bielsko-Biała, Poland
The implementation of the food safety management system – Hazard Analysis and Critical Control Points (HACCP) by AQUA S.A. was the first undertaking of this type in the water and sewage industry in Poland. In subsequent years, the HACCP system was extended to include the requirements of the ISO 22000 standard. The risk analysis performed as part of the implementation activities allowed to identify past, current and future threats to water safety, their sources, potential causes and consequences. It was a plan for further actions leading to increased water safety.
Keywords: ISO 22000, HACCP, water safety, risk analysis, quality management
Analysis of the periphyton structure for the bioindication of the stormwater system impact on the river
A. Kozłowska¹, E. Wojtaś¹, K. Jamka¹,², M. Staniszewski¹, J. Sierniawska¹, M. Zagojski¹, A. Raczkiewicz³, M. Piłat-Rożek³, R. Babko⁴, G. Łagód¹
¹Department of Water Supply and Wastewater Disposal, Faculty of Environmental Engineering and Energy, Lublin University of Technology, Nadbystrzycka 40B, 20-618 Lublin, Poland
²Institute of Rural Health, Jaczewskiego 2, 20-090 Lublin, Poland
³Department of Applied Mathematics, Faculty of Mathematics and Information Technology, Lublin University of Technology, Nadbystrzycka 38, 20-618 Lublin, Poland
⁴Department Fauna and Systematics of Invertebrates, National Academy of Sciences of Ukraine, 01030 Kyiv, Ukraine
Population growth, urbanization, and the intensification of economic activities contribute to the degradation of both aquatic and terrestrial ecosystems. Rainfall collects pollutants from urban surfaces, which are then transported into stormwater drainage systems, ultimately contaminating surface waters. Climate change further disrupts precipitation patterns, leading to alternating periods of drought and heavy rainfall, which exacerbates the problem of water pollution. Flora and fauna are forced to adapt to these changing environmental conditions, resulting in shifts in ecosystem structure. Environmental monitoring using bioindication—based on the analysis of community structures, such as periphyton—allows for the assessment of the impact of stormwater discharge and changes in pollution levels of water quality. These methods are important because they help with identification of areas in need of protection while being cost-effective and environmentally non-invasive. This study presents the results of bioindicative research on periphyton collected from the Bystrzyca River at four locations affected by stormwater discharge and one reference site located upstream from the outflow. Quantitative data on selected species of freshwater algae were analyzed using entropy-based indices to evaluate the structure of these communities.
Keywords: community structure, periphyton, bioindication, aquatic environment, surface water, stormwater system
Estimation of the concentration of fungal volatile organic compounds using electronic nose and machine learning
Z. Suchorab¹, A. Malec¹, Ł. Guz¹, M. Sak¹, D. Majerek², G. Łagód¹
¹Faculty of Environmental Engineering and Energy, Lublin University of Technology, ul. Nadbystrzycka 40B, 20-618 Lublin, Poland
²Faculty of Mathematics and Information Technology, Lublin University of Technology, ul. Nadbystrzycka 38, 20-618 Lublin, Poland
Microbiologically derived volatile organic compounds (mVOCs) are indicators of mycological contamination in buildings. This is an unfavourable phenomenon that negatively impacts the health of residents, as it is associated with Sick Building Syndrome, and buildings affected by it should undergo renovation. Diagnosing the presence of moulds in indoor air requires diagnostic testing, which is usually time-consuming and costly. Basic diagnostic methods include microbiological methods, involving the cultivation and counting of the colonies of fungi. Chemical testing, including gas chromatography, is another method for detecting chemical substances that are markers of fungal presence (including mVOCs). In this investigation we propose the use of a MOS gas sensor array (electronic nose) as a tool for detecting mycological contamination in indoor spaces. The signals obtained from the gas sensor array were then subjected to advanced analysis, involving the development of models to estimate mVOC concentrations. For this aims, the deterministic models based on linear regression without dimensionality reduction were developed, and then artificial intelligence methods as multilayer perceptron (MLP) and support vector machine (SVM)—were used. The analyses confirmed good efficiency of the AI models in prediction of fungal marker concentrations and lower concentration estimation errors compared to deterministic models based on linear regression.
Keywords: electronic nose, mould, microbiological volatile organic compounds, gas chromatography, machine learning
Environmental aspects of the biodegradation of sheep wool
M. Rom¹, J. Broda¹, A. Gawłowski¹, K. Kobiela-Mendrek¹, T. Kukulski¹, D. Biniaś¹, L. Przywara¹
¹University of Bielsko-Biala, Faculty of Materials, Civil and Environmental Engineering, Bielsko-Biała, PL
The rational use of low-quality coarse wool can be achieved by applying it as an organic fertiliser in agriculture and horticulture. When incorporated into soil, wool undergoes biodegradation, during which keratin is decomposed into peptides and amino acids. These nitrogen-rich compounds are gradually transformed into mineral nitrogen forms, providing essential nutrients for plant growth. The rate and extent of wool biodegradation depend on environmental conditions and the degree of fibre damage. To evaluate these factors, field studies were conducted using unwashed waste wool. The materials were mixed with peat and arable soil, and samples were collected periodically over one year. After cleaning, the samples were analysed using Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), and Fourier-Transformed Infrared Spectroscopy (FTIR). The analyses revealed distinct morphological and chemical changes in wool fibres during decomposition. The results provide insights into the progress of wool biodegradation in different soil conditions.
Keywords: sheep wool, fertilizer, biodegradation, Scanning Electron Microscopy (SEM), Energy-dispersive X-ray Spectroscopy (EDS), Fourier Transformed Infrared Spectroscopy
Utilization of waste PLA derived from 3D printing in the production of technological components: A Case Study on stirrers for Sequencing Batch Reactor (SBR)
Jacek Zaburko¹, Joanna Szulżyk-Cieplak¹, Roman Babko², Grzegorz Łagód³
¹Department of Technical Computer Science, Faculty of Mathematics and Information Technology, Lublin University of Technology, Nadbystrzycka 38, 20-618 Lublin, Poland
²Schmalhausen Institute of Zoology of the National Academy of Sciences of Ukraine, Vul. B. Khmelnytskogo, 15, 01601 Kyiv, Ukraine
³Department of Water Supply and Wastewater Disposal, Faculty of Environmental Engineering and Energy, Lublin University of Technology, Nadbystrzycka 40B, 20-618 Lublin, Poland
The rapid development of 3D printing, particularly Fused Deposition Modeling (FDM), has led to an increase in polymer waste generation. This study explores the potential for recycling waste polylactic acid (PLA) from failed prints into new filament to manufacture impellers for use in laboratory-scale Sequencing Batch Reactors (SBRs). The research focused on three key aspects: the mechanical reprocessing of PLA waste, testing the impeller’s durability under bioreactor conditions (exposure to activated sludge and raw wastewater), and analyzing its biodegradation after the operational cycle. The results showed that reprocessed PLA maintained sufficient mechanical strength for use in bioreactors and did not undergo significant biodegradation over a short period. From an economic standpoint, 3D printing impellers from recycled PLA offers clear advantages over traditional materials like stainless steel, especially for small-scale or customized production. Lower material costs, the elimination of complex machining, and the ability to quickly fabricate tailored geometries make this approach highly cost-effective. In conclusion, recycled PLA can be successfully reused to produce functional, durable components for biotechnological applications, supporting circular economy practices and offering a sustainable alternative for the additive manufacturing industry.
Keywords: recycling, circular economy, 3D printing, FDM, PLA, SBR bioreactor, impellers
Application of Passive Moss Biomonitoring in Tierra del Fuego (Patagonia)
Małgorzata Rajfur¹*, Vítězslav Plášek¹,², Paweł Świsłowski¹
¹Institute of Biology, University of Opole, Kominka 6, 6a st., 45-032 Opole, Poland
²Department of Biology and Ecology, University of Ostrava, Chittussiho 10, 710 00 Ostrava, Czech Republic
The aim of this study was to assess atmospheric air pollution in the Patagonia region using the moss species Lepyrodon lagurus as a biomonitor. 16 selected elements were determined using ICP-OES and a direct mercury analyzer. The results were evaluated using factor analysis (FA), enrichment factor (EF), and other pollution indices (CF, PLI, RI) to group the elements and associate them with possible emission sources and pollution levels. Half of the elements showed statistically significant differences depending on the sampling site. Although the observed concentrations of Co (0.947 mg/kg d.m.), Pb (1.37 mg/kg d.m.), Cr (1.68 mg/kg d.m.), Ni (1.94 mg/kg d.m.), and V (4.29 mg/kg d.m.) were relatively low compared to literature data, the area can no longer be considered pristine. The highest enrichment values reached 14.3 for Co, 6.50 for Pb, and 6.00 for Ni, indicating that anthropogenic activities, particularly road traffic, represent one of the main sources of atmospheric pollution in the region. This is the first biomonitoring survey using mosses conducted in Tierra del Fuego, and the findings highlight the need for further studies employing a broader grid and different moss species to identify the most sensitive biomonitor and establish long-term monitoring of atmospheric aerosol contamination in Patagonia.
Keywords: Air pollution, Biological indicator, Elements, Environmental quality, Lepyrodon lagurus, Tierra del Fuego
Integrating Moss Biomonitoring and Filter Sampling for Comparative Assessment of Atmospheric PAHs
Paweł Świsłowski¹*, Małgorzata Rajfur¹*, Tymoteusz Turlej², Oznur Isinkaralar³, Kaan Isinkaralar⁴, Sara Almasi⁵, Arianna Callegari⁵, Anca-Iulia Stoica⁶
¹Institute of Biology, University of Opole, Opole, PL
²Department of Power Systems and Environmental Protection Facilities, AGH University of Krakow, Cracow, PL
³Department of Landscape Architecture, Faculty of Engineering and Architecture, Kastamonu University, Kastamonu, TR
⁴Department of Environmental Engineering, Faculty of Engineering and Architecture, Kastamonu University, Kastamonu, TR
⁵Department of Civil Engineering and Architecture, University of Pavia, Pavia, IT
⁶Institute of Sanitary Engineering and Water Pollution Control (SIG), University of Natural Resources and Life Sciences, Vienna, AT
This research presents a six-month comparative study of polycyclic aromatic hydrocarbons (PAHs) in the urban atmosphere of Opole, Poland, applying two monitoring strategies: quartz fiber filter-based air sampling and active moss biomonitoring with Pleurozium schreberi, Sphagnum fallax, and Dicranum polysetum. Conducted from August 2021 to February 2022, the campaign covered autumn and winter, with PAH concentrations quantified via gas chromatography–mass spectrometry (GC–MS). Filters captured short-term fluctuations, notably sharp winter increases in high-molecular-weight PAHs such as benzo[a]pyrene (BaP), linked to heating activities and reduced dispersion. Particle sizes ranged from 0.16 to 73.6 μm (mean 0.71 μm). Mosses revealed cumulative uptake, with D. polysetum most effective for low- and medium-molecular-weight PAHs, followed by P. schreberi and S. fallax. Negative correlations were observed with solar radiation and temperature. Diagnostic ratios confirmed mainly pyrogenic origins, while D. polysetum also indicated petrogenic inputs. Combining moss biomonitoring and filter sampling provides a complementary framework for assessing urban air quality under changing meteorological conditions and supports the integration of moss-based methods into monitoring programs.
Keywords: Air Filters; Atmospheric Pollution; Environmental Monitoring; Urban Air Quality
Carbon-negative hemp concrete as a sustainable material that reduces heating energy demand
P. Brzyski
Lublin University of Technology, Faculty of Civil Engineering and Architecture, Nadbystrzycka 40 Street, 20-618 Lublin
The construction sector is responsible for significant energy consumption. Energy is consumed during the production of building materials, the construction process, and the use of buildings (e.g., heating). Energy is also consumed at the end of a building’s life cycle during demolition and disposal. In accordance with EU directives, efforts are being made to reduce the construction sector’s environmental impact. One way to promote sustainable development is to use raw materials and semi-finished products that are low processed. Plant-based raw materials minimize the embodied energy of building materials through a negative carbon footprint and low energy consumption during production. A popular plant-based material is hemp shives, which are obtained from industrial hemp stalks. In addition to their negative carbon footprint, hemp shives are characterized by high porosity and good insulating properties. Hemp shives are used as a filler in hemp concrete, which is primarily used for thermal insulation in timber frame walls. Using hemp concrete reduces a building’s environmental impact throughout its entire life cycle. This material has a negative carbon footprint during production, reduces heating energy demand during use, and can biodegrade after demolition or be crushed and reused at the end of its life cycle. This paper reviews the environmental parameters of hempcrete and calculates the energy demand for heating a house insulated with this material.
Keywords: Hemp shives, hemp concrete, carbon foot print, thermal insulation, energy demand for heating
Herbal plants: Tussilago farfara L. and Tanacetum vulgare L. as a source of information on cadmium contamination of ruderal habitats
M. Jaźwa1, P. Świsłowski1, K. Piątek2, A. Stadnicka-Futoma3, M. Rajfur1
1University of Opole, Opole, Poland
2Independent researcher, Jodłowa, Poland
3University of Rzeszow, Rzeszow, Poland
Tussilago farfara and Tanacetum vulgare are species of the Asteraceae family, widespread in Europe and also common in Poland. Both are used as herbal raw materials. In the case of Tussilago, the extracted parts are primarily the leaves (Farfarae folium) and the flower (Flos Farfarae), and are used as an expectorant. Tansy is used mainly externally; infusions were formerly used for parasites and digestive problems. To this day, it is used as a natural repellent and insecticide. Both species often occur in ruderal locations, making them susceptible to heavy metal contamination. These are usually easily accessible areas, such as roadsides, railway tracks, and farmsteads, from which the plants are collected for amateur herbal medicine. Plants of both species and soil samples were collected from sites with varying levels of human impact in southern and southeastern Poland. The content of heavy metals (Cu, Ni, Zn, Cd, Pb, Mn, Fe) was determined separately in tansy (in the above-ground parts, shoots, and soil), and in coltsfoot (in the inflorescences, underground parts, and soil). Metals in plant and soil samples were determined using atomic absorption spectroscopy (AAS). The conducted studies have shown that in both plants, the average concentration of cadmium is high, which indicates a high BCF value, indicating a high degree of accumulation. The calculated values were: from 1.29 (underground parts) to 1.59 (inflorescences) for Tussilago, and 1.23 (inflorescences) to 2.53 (aboveground parts) for Tanacetum. This means that these plants absorb metal from the soil intensively. In coltsfoot, higher values were recorded in the inflorescences, and the concentration in plant parts was, on average, higher than in the soil, which was also confirmed by high BCF values (BCF 1.44). Similarly, in the case of tansy, intense levels of cadmium accumulation were observed in the green parts of the plant and in the inflorescences. In some plant samples, the concentration of Cd exceeded the permissible values given for herbs in the Commission Regulation of 2023. Our results indicate that collecting coltsfoot and tansy from natural habitats is not recommended due to the risk of heavy metal accumulation, especially cadmium.
Keywords: plant accumulation, heavy metals, cadmium, Tussilago farfara L., Tanacetum vulgare, atomic absorption spectrometry
UV-assisted filtration as a tool for rainwater purification
E. Kudlek1, R. Rapacewicz1,2, H. Gadomska1, Ł. Lempart1,3
1Silesian University of Technology, Faculty of Energy and Environmental Engineering, Konarskiego 18, 44-100 Gliwice, Poland
2PB LEMTER, Mickiewicza 66, 41-902 Bytom, Poland
3Underwater Activities Center Association “Nurek Bytom”, Chorzowska 28a, 41-902 Bytom, Poland
Rainwater is a significant alternative water source with various potential applications that go beyond traditional uses like irrigation and hygiene. This study focused on purifying rainwater collected from the roof of a building located in an industrial area of Upper Silesia, Poland. The analysis of the collected samples revealed the presence of several organic micropollutants and heavy metals, indicating that this water was not safe for human contact. The purification process involved using filtration columns filled with different materials: filter glass (grain size 0.5–1.0 mm), activated carbon, and quartz sand. Additionally, the filtration was enhanced by exposure to UV radiation from low- and medium-pressure lamps. The effectiveness of the treatment was assessed by analyzing the removal rates of selected micropollutants. The results demonstrated that a combination of filtration through activated glass and activated carbon, along with UV irradiation, successfully eliminated polycyclic aromatic hydrocarbons (PAHs), phthalates, and phenolic compounds commonly found in rainwater. Furthermore, activated carbon effectively captured intermediate degradation products formed during the UV-induced breakdown of contaminants. The use of a high-pressure UV lamp also extended the operational lifespan of all tested filter materials. Acknowledgement: This research was financed by the National Centre for Research and Development, No. LIDER13/0126/2022.
Keywords: rainwater, UV-light, micropollutants, water reuse
Mining Waste to Resource: Copper Recovery Potential of a Copper-Tolerant Arthrobacter Isolated from a Gold–Copper Legacy Site
A. Ševců1, V. Velianyk1, V. Hlaváčková1
1Technical University of Liberec, Institute for Nanomaterials, Advanced Technologies and Innovation, Liberec, Czech Republic
Copper is a critical industrial resource, essential for electronics, renewable energy systems, construction, and transportation. Growing demand, together with declining ore grades, emphasizes the need for sustainable recovery methods that transform waste into a valuable secondary source. Microbial processes provide a promising alternative, combining resource recovery with environmentally friendly technology. In this study, a copper-tolerant Arthrobacter sp. (Microbacteriaceae, Actinobacteria) was isolated from an iron-rich crust at a former gold–copper mine in Zlaté Hory, Czech Republic. The strain’s copper resistance and potential for copper bioprecipitation were investigated. The minimum biofilm inhibitory concentration (MBIC) on nutrient agar supplemented with copper nitrate trihydrate [Cu(NO₃)₂·3H₂O] was <4 mM, while growth remained unaffected in nutrient broth with 1–4 mM copper, indicating a minimum inhibitory concentration (MIC) of ≥4 mM. Microscopic analyses (SEM, STEM) revealed intracellular copper nanoparticles with irregular, spherical, and elongated shapes, ranging from 10–100 nm. Energy-dispersive X-ray spectroscopy (EDX) confirmed significant intracellular copper accumulation, with a content of 34.9 wt%. These findings highlight Arthrobacter sp. as a promising candidate for copper recovery from mining residues and waste streams. By converting soluble copper into stable nanoparticles, this bacterium offers a sustainable pathway for securing copper supplies vital to modern technologies.
Keywords: Actinobacteria, Minimum biofilm inhibitory concentration (MBIC), Minimum inhibitory concentration (MIC), Heavy metal resistance
What Can Ferrocyanide Tell Us About Advanced Reduction Processes?
Veronika Leová1, Anna Kazdová1, Stanisław Wacławek1
1Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, 461 17, Liberec, Czech Republic
Advanced reduction processes (ARPs) are emerging as promising methods for degrading persistent pollutants in water, including per- and polyfluoroalkyl substances (PFAS). These processes rely on hydrated electrons (eaq)—highly reactive, short-lived species with exceptional reducing power capable of breaking down even the most chemically stable compounds. Hydrated electrons can be generated through the photolysis of aqueous solutions containing suitable reducing agents, such as sulfite, iodide, or ferrocyanide. However, this process typically requires high-energy UV irradiation, limiting the practical and economic feasibility of ARPs. In this work, we examined the UV photolysis of ferrocyanide ([Fe(CN)₆]⁴⁻), a well-known photosensitizer with a high absorption coefficient and quantum yield, for the degradation of perfluorooctanoic acid (PFOA) under various conditions. The influence of parameters such as pH and ferrocyanide concentration on ARP performance was systematically evaluated. Although ferrocyanide itself is not suitable for large-scale applications due to the potential release of toxic cyanide, the insights gained from this study enhance the mechanistic understanding of ARPs and support the further development of more energy-efficient and environmentally compatible photosensitizers for next-generation water treatment technologies.
Keywords: Advanced reduction processes; hydrated electron; ferrocyanide; PFAS degradation; photochemistry; water treatment
From Coffee Waste to Biopolymers: Designing Eco-Friendly Materials for Environmental Applications
Andrzej Kos1, Włodzimierz Biniaś1, Klaudiusz Grübel1
1University of Bielsko-Biala, Faculty of Materials, Civil and Environmental Engineering, Bielsko-Biała, Poland
The aim of this study was to develop eco-friendly biopolymers based on coffee husks (so-called silver skin) as an alternative to traditional plastics by examining their mechanical, thermal, and biodegradability properties. The study confirmed that eco-friendly biopolymers can be produced from plant waste, such as coffee husks, using natural binders such as gluten and starch. Composites containing gluten and glycerol demonstrated the best functional properties, characterized by high elasticity, fracture resistance, and dimensional stability after drying. Using glycerol as a plasticizer allowed the material to maintain its long-term elasticity, while the addition of salt increased the strength of the protein bonds. This material represents a promising alternative to conventional plastics and, due to its biodegradability and the use of waste materials, aligns with the principles of a circular economy. Further work will focus on optimizing the composition and molding parameters to enable practical application of the developed biopolymers in production.
Keywords: silver skin, biopolymers, biodegradability, gluten, glycerol
Concentration of Heavy Metals in Moss Samples on the Campus of the University of Opole
Alicja Wolny1, Paweł Świsłowski1
1University of Opole, Opole, Poland
Mosses are capable of accumulating many heavy metals like mercury, lead and cadmium, which are commonly recognised as harmful to the environment. The purpose of this research was to determine if the concentration of heavy metals in moss samples exposed to natural factors differs from that in samples not entirely exposed. The exposure occurred during the Polish students’ holiday, “Piastonalia,” a time when many students visit the campus to enjoy concerts, sometimes using devices like smoke machines. There is also much more traffic than usual. The goal was to check if the air is more polluted during similar events. It is essential to note that the study shown is local and on a small scale, but it prompts further research on that matter in the future.
Keywords: mosses, active biomonitoring, heavy metal, air pollution
Application of a soil-zeolite column for immobilization of elements contained in landfill leachates
Iwona Kamińska, Marcin K. Widomski, Rafał Panek
Lublin University of Technology, Lublin, PL
Soil and groundwater contamination with metals, especially at landfills, poses a serious environmental threat, mainly because these elements are toxic, accumulate in living organisms, and have the potential to cause long-term effects, such as carcinogenicity or hormonal disorders. Therefore, alternative ways of managing clay raw materials used for the construction of insulation barriers modified with various additives, including synthetic zeolites, are being sought. Modified clay barriers, enriched with recycled zeolites, can be an effective method of reducing metal migration due to their adsorption properties and the ability to immobilize pollutants. The aim of the study was to assess the possibility of using clay soils and soil mixtures with varying amounts of synthetic zeolite additives to immobilize selected elements contained in landfill leachate. Four sorbent substrates were tested, a sandy loam sampled in Chotyłów Poland, its mixture with 10 and 20% by mass of synthetic zeolite NaP1, and synthetic zeolite NaP1. The following elements identified in the leachate were selected for the study: Al, P, Mn, Fe, Sn, and Ba. The elemental concentrations were determined using inductively coupled plasma mass spectrometry (ICP-MS) in accordance with the procedure EPA 6020. The results clearly showed that the sorption process was quite effective for most elements on all tested sorbents, with the lowest sorption observed for barium on clay soil. The addition of zeolite significantly improved the sorption efficiency for this metal. The other elements showed a relatively high degree of sorption on all analyzed sorbents, while the highest sorption capacity was observed for phosphorus on NaP1 zeolite. Based on the results obtained, it was concluded that the tested sorbents may be promising materials for the immobilization of pollutants contained in landfill leachate, which are raw materials for the construction of isolation barriers.
Keywords: sorbents, sorption properties, heavy metals, landfill leachate, synthetic zeolite, clay soil